The actress, then keen to make her big break, was shot by photographer Sean McCall

Her unblemished skin is also a distant memory. Miss Jolie, now 32, is understood to have at least 13 tattoos decorating her body, including the geographical co-ordinates of her children's birthplaces etched on to her left shoulder.

Angelina's teens proved a tumultuous time for her - at 14, Angelina was permitted to move in her older boyfriend into her mother Marcheline Bertrand's LA home and later dropped out of acting classes at Lee Strasberg Theatre Institute.

Estranged from her father, she has since admitted to suffering bouts of depression, but went on to return to theatre studies and graduate from Beverly Hills High School.